Hysteresis in the surfactant-induced volume transition of hydrogels

J Phys Chem B. 2015 Jan 29;119(4):1717-25. doi: 10.1021/jp5087416. Epub 2015 Jan 17.

Abstract

The discontinuous uptake and release of surfactants by hydrogels and the accompanying discontinuous volume transition is known to occur with a hysteresis. We have performed a theoretical analysis in order to find the mechanistic origin of this phenomenon. Using a mean-field model, we have quantitatively reproduced the experimental behavior by considering the cost of elastically deforming the gel material to allow phase coexistence. The major part of the hysteresis is due to the high phase coexistence cost of the swelling transition, since in this direction the coexistence cost depends not only on the elasticity of the network (being a weak force in comparison) but also on the entropy of the monovalent nonsurfactant electrolyte present in the system.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Biomechanical Phenomena
  • Hydrogels / chemistry*
  • Surface-Active Agents / chemistry*
  • Thermodynamics

Substances

  • Hydrogels
  • Surface-Active Agents