cis-Semihydrogenation of alkynes with amine borane complexes catalyzed by gold nanoparticles under mild conditions

Chem Commun (Camb). 2015 Feb 11;51(12):2384-7. doi: 10.1039/c4cc08163c.

Abstract

Supported gold nanoparticles catalyze the semihydrogenation of alkynes to alkenes with ammonia borane or amine borane complexes in excellent yields and under mild conditions. Internal alkynes provide cis-alkenes, making this protocol an attractive alternative of the classical Lindlar's hydrogenation.