A high-temperature molecular ferroelectric Zn/Dy complex exhibiting single-ion-magnet behavior and lanthanide luminescence

Abstract

Multifunctional molecular ferroelectrics are exciting materials synthesized using molecular chemistry concepts, which may combine a spontaneous electrical polarization, switched upon applying an electric field, with another physical property. A high-temperature ferroelectric material is presented that is based on a chiral Zn(2+) /Dy(3+) complex exhibiting Dy(3+) luminescence, optical activity, and magnetism. We investigate the correlations between the electric polarization and the crystal structure as well as between the low-temperature magnetic slow relaxation and the optical properties.

Keywords: chirality; lanthanides; luminescence; molecular ferroelectrics; single-ion magnets.