To reveal the effect of alloy element on the morphology of in situ TiB2 particles, a series of TiB2 particles with various morphology were obtained via controlling synthesis process. Si and Cu can affect the morphology transformation of TiB2 particles significantly. Si preferentially adsorbed on (101¯1), (112¯0) and (12¯13¯) planes resulting in the polyhedron morphology of TiB2. Cu adsorbed on (101¯0) preferentially leading to the minimum aspect (the ratio of the diameter and thickness).
Keywords: Chamfered edges and corners; Element adsorption; Growth geometric conditions; Shape control; TiB(2) morphology.
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