A monolith immobilised iridium Cp* catalyst for hydrogen transfer reactions under flow conditions

Org Biomol Chem. 2015 Feb 14;13(6):1768-77. doi: 10.1039/c4ob02376e.

Abstract

An immobilised iridium hydrogen transfer catalyst has been developed for use in flow based processing by incorporation of a ligand into a porous polymeric monolithic flow reactor. The monolithic construct has been used for several redox reductions demonstrating excellent recyclability, good turnover numbers and high chemical stability giving negligible metal leaching over extended periods of use.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Catalysis
  • Hydrogen / chemistry*
  • Iridium / chemistry*
  • Ligands
  • Molecular Structure
  • Organometallic Compounds / chemistry*
  • Polymers / chemistry*
  • Porosity
  • Surface Properties

Substances

  • Ligands
  • Organometallic Compounds
  • Polymers
  • Iridium
  • Hydrogen