Carboxymethylagarose-AuNPs generated through green route for selective detection of Hg2+ in aqueous medium with a blue shift

Jai Prakash Chaudhary; Anshu Kumar; Parimal Paul; Ramavatar Meena

doi:10.1016/j.carbpol.2014.10.016

Carboxymethylagarose-AuNPs generated through green route for selective detection of Hg2+ in aqueous medium with a blue shift

Carbohydr Polym. 2015 Mar 6:117:537-542. doi: 10.1016/j.carbpol.2014.10.016. Epub 2014 Oct 18.

Authors

Jai Prakash Chaudhary¹, Anshu Kumar², Parimal Paul³, Ramavatar Meena⁴

Affiliations

¹ Scale-Up & Process Engineering Unit, CSIR-Central Salt and Marine Chemicals Research Institute, G. B. Marg, Bhavnagar 364 002, India; Academy of Scientific & Innovative Research-Central Salt and Marine Chemicals Research Institute, G. B. Marg, Bhavnagar 364 002, India.
² Academy of Scientific & Innovative Research-Central Salt and Marine Chemicals Research Institute, G. B. Marg, Bhavnagar 364 002, India; Analytical Discipline and Centralized Instrument Facility, CSIR Central Salt & Marine Chemicals Research Institute, Bhavnagar 364 002, India.
³ Academy of Scientific & Innovative Research-Central Salt and Marine Chemicals Research Institute, G. B. Marg, Bhavnagar 364 002, India; Analytical Discipline and Centralized Instrument Facility, CSIR Central Salt & Marine Chemicals Research Institute, Bhavnagar 364 002, India. Electronic address: ppaul@csmcri.org.
⁴ Scale-Up & Process Engineering Unit, CSIR-Central Salt and Marine Chemicals Research Institute, G. B. Marg, Bhavnagar 364 002, India; Academy of Scientific & Innovative Research-Central Salt and Marine Chemicals Research Institute, G. B. Marg, Bhavnagar 364 002, India. Electronic address: rmeena@csmcri.org.

PMID: 25498668
DOI: 10.1016/j.carbpol.2014.10.016

Abstract

We report here a facile, rapid, cost-effective method via a green route for the selective detection of Hg(2+) in aqueous media. In this study carboxymethylagarose (CMA) is used to generate gold nanoparticles and subsequently to act as a stabilizer for the CMA-functionalized gold nanoparticles (CMA-AuNPs). The resulting CMA-AuNPs was characterized by UV-visible, X-ray diffraction, transmission electron microscopy (TEM), dynamic light scattering (DLS), atomic force microscopy (AFM) and zeta potential measurements. Zeta potential value (∼ -73 mv) of CMA-AuNPs in the aqueous medium shows its higher stability. When CMA-AuNPs were exposed to an aqueous Hg(2+), a blue shift for its localized surface plasmon resonance absorbance (LSPR) band is observed along with significant colour change of the solution. The probe enables to detect Hg(2+) in the range of 0.01-100 ppm even in spiked lake water samples. This study offers a sustainable and eco-friendly route for selective detection of Hg(2+) in aqueous solution and may find potential application towards water purification.

Keywords: Amalgam; Blue shift; CMA-AuNPs; Green process; Mercury sensor.

Publication types

Research Support, Non-U.S. Gov't