Direct radical acetoxyphosphorylation of styrenes mediated by manganese(III)

J Org Chem. 2015 Jan 16;80(2):1214-20. doi: 10.1021/jo5023298.

Abstract

Direct radical acetoxyphosphorylation of styrenes mediated by Mn(OAc)3 with diphenylphosphine oxide and dialkyl phosphites was described, and a new type of difunctionalization of alkenes was achieved.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Alkenes / chemistry*
  • Manganese / chemistry*
  • Molecular Structure
  • Organophosphorus Compounds / chemistry*
  • Phosphites / chemistry*
  • Phosphorylation
  • Styrenes / chemistry*

Substances

  • Alkenes
  • Organophosphorus Compounds
  • Phosphites
  • Styrenes
  • Manganese
  • triphenylphosphine oxide