Liquid crystal-gated-organic field-effect transistors with in-plane drain-source-gate electrode structure

ACS Appl Mater Interfaces. 2015 Jan 14;7(1):504-10. doi: 10.1021/am506609s. Epub 2014 Dec 23.

Abstract

We report planar liquid crystal-gated-organic field-effect transistors (LC-g-OFETs) with a simple in-plane drain-source-gate electrode structure, which can be cost-effectively prepared by typical photolithography/etching processes. The LC-g-OFET devices were fabricated by forming the LC layer (4-cyano-4'-pentylbiphenyl, 5CB) on top of the channel layer (poly(3-hexylthiophene), P3HT) that was spin-coated on the patterned indium-tin oxide (ITO)-coated glass substrates. The LC-g-OFET devices showed p-type transistor characteristics, while a current saturation behavior in the output curves was achieved for the 50-150 nm-thick P3HT (channel) layers. A prospective on/off ratio (>1 × 10(3)) was obtained regardless of the P3HT thickness, whereas the resulting hole mobility (0.5-1.1 cm(2)/(V s)) at a linear regime was dependent on the P3HT thickness. The tilted ordering of 5CB at the LC-P3HT interfaces, which is induced by the gate electric field, has been proposed as a core point of working mechanism for the present LC-g-OFETs.

Keywords: 5CB; LC-g-OFET; dipole; liquid crystal; organic transistor.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Crystallization
  • Electric Capacitance
  • Electric Impedance
  • Electrodes
  • Indium / chemistry
  • Liquid Crystals*
  • Materials Testing
  • Microscopy
  • Nanotechnology / methods*
  • Organic Chemicals / chemistry*
  • Semiconductors
  • Temperature
  • Tin Compounds / chemistry
  • Transistors, Electronic*

Substances

  • Organic Chemicals
  • Tin Compounds
  • Indium
  • stannic oxide