Donor-acceptor (D-A) structures were obtained by alternating arrays of hexa-peri-hexabenzocoronene (HBC) and benzo[c][1,2,5]thiadiazole (BTZ). Optoelectronic investigations revealed a charge transfer due to strong push-pull interactions. 2 D wide-angle X-ray scattering (WAXS) data indicated an arrangement in liquid-crystalline columnar assemblies, in which the π-stacking distances and molecular orientation depend on the number of HBC units in the molecules.
Keywords: charge transfer; donor-acceptor systems; hexa-peri-hexabenzocoronene; liquid crystals; self-assembly.
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