Abstract
A highly efficient CH3CN-promoted hexamethyldisilazane per-O-trimethylsilylation of amino sugars was developed. Its applications in homogenous N-functionalisation and a concise synthesis of glucosamine 6-phosphate are described.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Acetonitriles / chemistry
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Amino Sugars / chemistry*
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Glucosamine / analogs & derivatives
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Glucosamine / chemical synthesis
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Glucosamine / chemistry
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Glucose-6-Phosphate / analogs & derivatives
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Glucose-6-Phosphate / chemical synthesis
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Glucose-6-Phosphate / chemistry
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Nitrogen / chemistry
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Organosilicon Compounds / chemistry
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Oxygen / chemistry
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Pyridines / chemistry
Substances
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Acetonitriles
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Amino Sugars
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Organosilicon Compounds
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Pyridines
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glucosamine 6-phosphate
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Glucose-6-Phosphate
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hexamethylsilazane
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Glucosamine
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Nitrogen
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pyridine
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Oxygen