Multifunctional membranes based on photosensitive crown-ether derivatives with advanced properties

Abstract

This review discusses recent works on monolayer, multilayer and polymer films of various crown-ether derivatives. Preparation and investigation of such membrane nanostructures based on photosensitive and surface-active crown-ethers is a rapidly growing field at the "junction" of colloids and polymers, materials sciences and nanotechnology. These membranes can serve as convenient models for studying the self-organization and molecular recognition processes at interfaces that are typical for biomembranes. The results obtained for such structures by absorption and fluorescence spectroscopy, atomic force and Brewster-angle microscopy, surface pressure and surface potential isotherm measurements have been described. The possibility of developing multifunctional materials possessing advanced properties has been demonstrated.

Keywords: Cown-ethers; Fluorescence; Ion-selectivity; Membranes; Monolayers; Photosensitivity.