Crystal structure of 4-(2,2-di-methyl-propanamido)-pyridin-3-yl N,N-diiso-propyl-dithio-carbamate

Gamal A El-Hiti; Keith Smith; Amany S Hegazy; Mohammed Baashen; Benson M Kariuki

doi:10.1107/S1600536814019321

Crystal structure of 4-(2,2-di-methyl-propanamido)-pyridin-3-yl N,N-diiso-propyl-dithio-carbamate

Acta Crystallogr Sect E Struct Rep Online. 2014 Aug 30;70(Pt 9):o1069-70. doi: 10.1107/S1600536814019321. eCollection 2014 Sep 1.

Authors

Gamal A El-Hiti¹, Keith Smith², Amany S Hegazy², Mohammed Baashen³, Benson M Kariuki²

Affiliations

¹ Cornea Research Chair, Department of Optometry, College of Applied Medical Sciences, King Saud University, PO Box 10219, Riyadh 11433, Saudi Arabia.
² School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff CF10 3AT, Wales.
³ Criminal Evidence, Ministry of Interior, Riyadh 11632, PO Box 86985, Saudi Arabia.

Abstract

In the title compound, C17H27N3OS2, the amide group is approximately coplanar with the pyridine ring [dihedral angle = 1.6 (1)°], whereas the di-thio-carbamate group is nearly perpendicular to the pyridine ring [dihedral angle = 76.7 (1)°]. In the crystal, pairs of weak C-H⋯O hydrogen bonds link the mol-ecules into inversion dimers.

Keywords: crystal structure; dithiocarbamate; hydrogen bonding; pyridine derivatives.