Crystal structure of ethyl (E)-4-(4-chlorophen-yl)-4-meth-oxy-2-oxobut-3-enoate

Acta Crystallogr Sect E Struct Rep Online. 2014 Aug 16;70(Pt 9):o1025. doi: 10.1107/S1600536814017280. eCollection 2014 Sep 1.

Abstract

In the title compound, C13H13ClO4, the dihedral angle between the chloro-benezene ring and the least-squares plane through the 4-meth-oxy-2-oxobut-3-enoate ethyl ester residue (r.m.s. deviation = 0.0975 Å) is 54.10 (5)°. In the crystal, mol-ecules are connected by meth-oxy-ketone and benzene-carboxyl-ate carbonyl C-H⋯O inter-actions, generating a supra-molecular layer in the ac plane.

Keywords: 4-meth­oxy-2-oxobut-3-enoate ethyl ester; benzene–carboxyl­ate carbonyl inter­actions; crystal structure; meth­oxy–ketone inter­actions.