Synthesis, structures, and reactivity of the base-stabilized silanone molybdenum complexes

Takako Muraoka; Keisuke Abe; Haruhiko Kimura; Youhei Haga; Keiji Ueno; Yusuke Sunada

doi:10.1039/c4dt02159b

Synthesis, structures, and reactivity of the base-stabilized silanone molybdenum complexes

Dalton Trans. 2014 Nov 28;43(44):16610-3. doi: 10.1039/c4dt02159b.

Authors

Takako Muraoka¹, Keisuke Abe, Haruhiko Kimura, Youhei Haga, Keiji Ueno, Yusuke Sunada

Affiliation

¹ Division of Molecular Science, Graduate School of Science and Technology, Gunma University, Kiryu 376-8515, Japan. ueno@gunma-u.ac.jp.

PMID: 25307405
DOI: 10.1039/c4dt02159b

Abstract

Base-stabilized silanone molybdenum complexes were synthesized by the oxygenation of the M=Si bond in the silyl(silylene)molybdenum complex with 1 eq. of PNO in the presence of Lewis base L. The PNO-coordinated silanone complex (L = PNO) was converted to cis-[Cp*(OC)2Mo{OSiMes2(OSiMe3)}(PMe3)] in the presence of excess PMe3.