Synthesis and dynamic behavior of an anthyridine-ligated ruthenium complex

Shota Hirakawa; Take-aki Koizumi

doi:10.1021/ic5011743

Synthesis and dynamic behavior of an anthyridine-ligated ruthenium complex

Inorg Chem. 2014 Oct 20;53(20):10788-90. doi: 10.1021/ic5011743. Epub 2014 Oct 9.

Authors

Shota Hirakawa¹, Take-aki Koizumi

Affiliation

¹ Chemical Resources Laboratory, Tokyo Institute of Technology , 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan.

PMID: 25299852
DOI: 10.1021/ic5011743

Abstract

A ruthenium complex containing a 1,9,10-anthyridine derivative, [Ru(L)(bpy)2](PF6)2 ([1](PF6)2; L = 1,13,14-triazadibenz[a,j]anthracene, bpy = 2,2'-bipyridyl), was synthesized. X-ray crystal structural analysis of [1](PF6)2 showed that L is coordinated to the Ru center as a bidentate ligand. When [1](PF6)2 was dissolved in acetonitrile, a new complex incorporating one acetonitrile molecule, [Ru(L)(CH3CN)(bpy)2](PF6)2 ([2](PF6)2), was formed. X-ray crystallographic data revealed that, in [2](PF6)2, L is coordinated to the Ru center in a monodentate fashion. The coordinated L in [2](PF6)2 shows a unique haptotropic rearrangement in an acetonitrile solution.