Zinc oxide/silver nanoarrays as reusable SERS substrates with controllable 'hot-spots' for highly reproducible molecular sensing

Ahmad Esmaielzadeh Kandjani; Mahsa Mohammadtaheri; Akshi Thakkar; Suresh Kumar Bhargava; Vipul Bansal

doi:10.1016/j.jcis.2014.09.017

Zinc oxide/silver nanoarrays as reusable SERS substrates with controllable 'hot-spots' for highly reproducible molecular sensing

J Colloid Interface Sci. 2014 Dec 15:436:251-7. doi: 10.1016/j.jcis.2014.09.017. Epub 2014 Sep 17.

Authors

Ahmad Esmaielzadeh Kandjani¹, Mahsa Mohammadtaheri², Akshi Thakkar³, Suresh Kumar Bhargava⁴, Vipul Bansal⁵

Affiliations

¹ Ian Potter NanoBioSensing Facility and NanoBiotechnology Research Laboratory (NBRL), School of Applied Sciences, RMIT University, GPO Box 2476 V, Melbourne, VIC 3001, Australia; Centre for Advanced Materials and Industrial Chemistry, School of Applied Sciences, RMIT University, GPO Box 2476 V, Melbourne, VIC 3001, Australia. Electronic address: s3301407@student.rmit.edu.au.
² Ian Potter NanoBioSensing Facility and NanoBiotechnology Research Laboratory (NBRL), School of Applied Sciences, RMIT University, GPO Box 2476 V, Melbourne, VIC 3001, Australia. Electronic address: s3405574@student.rmit.edu.au.
³ Ian Potter NanoBioSensing Facility and NanoBiotechnology Research Laboratory (NBRL), School of Applied Sciences, RMIT University, GPO Box 2476 V, Melbourne, VIC 3001, Australia. Electronic address: akshi.thakkar@rmit.edu.au.
⁴ Centre for Advanced Materials and Industrial Chemistry, School of Applied Sciences, RMIT University, GPO Box 2476 V, Melbourne, VIC 3001, Australia. Electronic address: suresh.bhargava@rmit.edu.au.
⁵ Ian Potter NanoBioSensing Facility and NanoBiotechnology Research Laboratory (NBRL), School of Applied Sciences, RMIT University, GPO Box 2476 V, Melbourne, VIC 3001, Australia. Electronic address: vipul.bansal@rmit.edu.au.

PMID: 25278363
DOI: 10.1016/j.jcis.2014.09.017

Abstract

Hypothesis: The reproducible surface enhanced Raman scattering (SERS)-based sensing of an analyte relies on high quality SERS substrates that offer uniformity over large areas. Uniform ZnO nanoarrays are expected to offer an appropriate platform for SERS sensing. Moreover, since ZnO has good photocatalytic properties, controllable decoration of silver nanoparticles on ZnO nanoarrays may offer an additional opportunity to clean up SERS substrates after each sensing event.

Experiments: This study employs a facile soft chemical synthesis strategy to fabricate Raman-active and recyclable ZnO/Ag nanorod arrays as reproducible SERS substrates. Arrays of ZnO nanorods were synthesized using hydrothermal method, which was followed by controllable decoration of ZnO with silver nanoparticles (AgNPs) using an electroless plating technique.

Findings: The uniform density of SERS-active 'hot-spots' on ZnO nanoarrays could be controlled on a large 1×1 cm(2) substrate. These ZnO/Ag nanoarrays showed high reproducibility (0.132 RSD) towards acquiring SERS spectra of rhodamine B (RB) at 30 random locations on a single substrate. The photocatalytic nature of ZnO/Ag semiconductor/metal hybrid endowed these substrates with reusability characteristics. By controlling metal loading on a semiconductor surface, photocatalytic activity and high SERS performance can be integrated within a single package to obtain high quality, reproducible, stable and recyclable SERS substrates.

Keywords: Nanoarrays; Photocatalysis; Reusability; Sensing; Silver; Surface enhanced Raman scattering (SERS); Zinc oxide; ZnO/Ag hybrid.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Microscopy, Electron, Scanning
Nanostructures / chemistry*
Reproducibility of Results
Silver / chemistry*
Zinc Oxide / chemistry*

Substances

Silver
Zinc Oxide