Bis(2-amino-4-phenyl-1,3-thia-zol-3-ium) tetra-chlorido-palladate(II)

Acta Crystallogr Sect E Struct Rep Online. 2014 Jul 11;70(Pt 8):m295. doi: 10.1107/S1600536814015360. eCollection 2014 Aug 1.

Abstract

The title compound, (C9H9N2S)2[PdCl4], consists of two monoprotonated 2-amino-4-phenyl-1,3-thia-zole molecules and one tetra-chlorido-palladate anion. The organic molecules exhibit a dihedral angle between the main rings planes of 31.82 (9)°. In the anion, the Pd(II) atom is located on a crystallographic centre of symmetry with a square-planar geometry. In the crystal, the anions and cations are connected through bifurcated N-H⋯Cl hydrogen bonds, and these inter-actions lead to hydrogen-bonded tapes of cations and anions along [100].

Keywords: crystal structure.