Crystal structure of a layered coordination polymer based on a 4(4) net containing Cd(2+) ions and 1,5-bis-(pyridin-4-yl)pentane linkers

William T A Harrison; M John Plater; Ben M deSilva deSilva; Mark R St J Foreman

doi:10.1107/S1600536814014779

Crystal structure of a layered coordination polymer based on a 4(4) net containing Cd(2+) ions and 1,5-bis-(pyridin-4-yl)pentane linkers

Acta Crystallogr Sect E Struct Rep Online. 2014 Jul 19;70(Pt 8):80-3. doi: 10.1107/S1600536814014779. eCollection 2014 Aug 1.

Authors

William T A Harrison¹, M John Plater¹, Ben M deSilva deSilva¹, Mark R St J Foreman¹

Affiliation

¹ Department of Chemistry, University of Aberdeen, Meston Walk, Aberdeen AB24 3UE, Scotland.

Abstract

The title compound, poly[[di-aqua-bis-[1,5-bis-(pyridin-4-yl)pentane-κ(2) N:N']cadmium] bis-(perchlorate) 1,5-bis-(pyridin-4-yl)pentane ethanol mono-solvate], [Cd(C15H18N2)2(H2O)2](ClO4)2·C15H18N2·C2H6O, is a layered coordination polymer built up from highly squashed 4(4) nets in which the octa-hedral trans-CdO2N4 nodes (Cd site symmetry -1) are linked by the bifunctional ligands, forming infinite (110) sheets. The cationic sheets are charge-balanced by inter-layer perchlorate ions. A free 1,5-bis-(pyridin-4-yl)pentane mol-ecule and an ethanol mol-ecule of crystallization are also found in the inter-sheet region. A number of O-H⋯O, O-H⋯N and C-H⋯O hydrogen bonds help to consolidate the layered structure.

Keywords: Cadmium; crystal structure; flexible ligand; layered coordination polymer.