Supramolecular polymers as surface coatings: rapid fabrication of healable superhydrophobic and slippery surfaces

Adv Mater. 2014 Nov 19;26(43):7358-64. doi: 10.1002/adma.201401366. Epub 2014 Sep 18.

Abstract

Supramolecular polymerization for non-wetting surface coatings is described. The self-assembly of low-molecular-weight gelators (LMWGs) with perfluorinated side chains can be utilized to rapidly construct superhydrophobic, as well as liquid-infused slippery surfaces within minutes. The lubricated slippery surface exhibits impressive repellency to biological li-quids, such as human serum and blood, and very fast self-healing.

Keywords: functional supramolecular polymers; gelators; lotus effect; slippery surfaces; superhydrophobic surface.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Amidines / chemical synthesis
  • Amidines / chemistry
  • Biomimetic Materials / chemistry
  • Caryophyllaceae
  • Cyclohexanes / chemical synthesis
  • Cyclohexanes / chemistry
  • Hydrogen Bonding
  • Hydrophobic and Hydrophilic Interactions
  • Lipids / chemistry
  • Lubrication / methods
  • Microscopy, Electron, Scanning
  • Microscopy, Electron, Transmission
  • Microwaves
  • Molecular Structure
  • Polymers / chemical synthesis
  • Polymers / chemistry*
  • Surface Properties
  • Water / chemistry

Substances

  • Amidines
  • Cyclohexanes
  • Lipids
  • Polymers
  • Water