Physico-chemical properties of various palm-based diacylglycerol oils in comparison with their corresponding palm-based oils

Food Chem. 2011 Aug 1;127(3):1031-8. doi: 10.1016/j.foodchem.2011.01.076. Epub 2011 Jan 26.

Abstract

Palm-based diacylglycerol (P-DAG) oils were produced through enzymatic glycerolysis of palm kernel oil (PKO), palm oil (PO), palm olein (POL), palm mid fraction (PMF) and palm stearin (PS). High purity DAG (83-90%, w/w) was obtained and compared to palm-based oils (P-oil) had significantly (P<0.05) different fatty acid composition (FAC), iodine value (IV) and slip melting point (SMP). Solid fat content (SFC) profiles of P-DAG oils as compared to P-oils had less steep curves with lower SFC at low temperature range (5-10°C) and the higher complete melting temperatures. Also, P-DAG oils in contrast with P-oils showed endothermic as well as exothermic peaks with higher transition temperatures and significantly (P<0.05) higher crystallisation onsets, heats of fusion, and heats of crystallisation. Crystal forms for P-DAG oils were mostly in the β form.

Keywords: Diacylglycerol composition; Palm-based diacylglycerol oils; Physico-chemical properties.