Highly regioselective 1,3-dipolar cycloaddition of diphenylnitrilimine to Sc3N@I(h)-C80 affording a very stable, unprecedented pyrazole-ring fused derivative of endohedral metallofullerenes

Bin Liu; Hailin Cong; Xiaofang Li; Bing Yu; Lipiao Bao; Wenting Cai; Yunpeng Xie; Xing Lu

doi:10.1039/c4cc06134a

Highly regioselective 1,3-dipolar cycloaddition of diphenylnitrilimine to Sc3N@I(h)-C80 affording a very stable, unprecedented pyrazole-ring fused derivative of endohedral metallofullerenes

Chem Commun (Camb). 2014 Oct 28;50(84):12710-3. doi: 10.1039/c4cc06134a.

Authors

Bin Liu¹, Hailin Cong, Xiaofang Li, Bing Yu, Lipiao Bao, Wenting Cai, Yunpeng Xie, Xing Lu

Affiliation

¹ Key Laboratory of Theoretical Chemistry and Molecular Simulation of Ministry of Education, Hunan Province College Key Laboratory of QSAR/QSPR, School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan, Hunan 411201, China. lixiaofang@iccas.ac.cn.

PMID: 25198829
DOI: 10.1039/c4cc06134a

Abstract

Formation of a very stable, unprecedented pyrazole-ring fused derivative of endohedral metallofullerenes was achieved by the first 1,3-dipolar cycloaddition reaction of Sc3N@C80 with diphenylnitrilimine in a highly regioselective manner.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Crystallography, X-Ray
Cycloaddition Reaction
Fullerenes / chemistry*
Imines / chemistry*
Molecular Conformation
Pyrazoles / chemistry*
Scandium / chemistry
Stereoisomerism

Substances

Fullerenes
Imines
Pyrazoles
pyrazole
Scandium