Magnetic hardening induced by nonmagnetic organic molecules

Phys Rev Lett. 2013 Sep 6;111(10):106805. doi: 10.1103/PhysRevLett.111.106805. Epub 2013 Sep 4.

Abstract

We reveal for the first time through a theoretical first-principles study that the adsorption of a nonmagnetic π-conjugated organic molecule on a ferromagnetic surface locally increases the strength of the magnetic exchange interaction between the magnetic atoms binding directly to the molecule. This magnetic hardening effect leads to the creation of a local molecular mediated magnetic unit with a stable magnetization direction and an enhanced barrier for the magnetization switching as compared to the clean surface. Remarkably, such a hybrid organic-ferromagnetic system exhibits also a spin-filter functionality with sharp spin-split molecularlike electronic features at the molecular site.