N-Methyl-2-(1-methyl-3-phenyl-prop-2-en-1-yl-idene)hydrazinecarbo-thio-amide

Fillipe Vieira Rocha; Adelino Vieira de Godoy Netto; Johannes Beck; Jörg Daniels; Adriano Bof de Oliveira

doi:10.1107/S1600536814013889

N-Methyl-2-(1-methyl-3-phenyl-prop-2-en-1-yl-idene)hydrazinecarbo-thio-amide

Acta Crystallogr Sect E Struct Rep Online. 2014 Jun 21;70(Pt 7):o800. doi: 10.1107/S1600536814013889. eCollection 2014 Jul 1.

Authors

Fillipe Vieira Rocha¹, Adelino Vieira de Godoy Netto¹, Johannes Beck², Jörg Daniels², Adriano Bof de Oliveira³

Affiliations

¹ Instituto de Química, Universidade Estadual Paulista, Rua Francisco Degni s/n, 14801-970 Araraquara-SP, Brazil.
² Institut für Anorganische Chemie, Universität Bonn, Gerhard-Domagk-Strasse 1, D-53121 Bonn, Germany.
³ Departamento de Química, Universidade Federal de Sergipe, Av. Marechal Rondon s/n, Campus, 49100-000 São Cristóvão-SE, Brazil.

Abstract

In the title compound, C12H15N3S, the mol-ecule deviates slightly from planarity, with a maximum deviation from the mean plane of the non-H atoms of 0.2756 (6) Å for the S atom and a torsion angle for the N-N-C-N fragment of -7.04 (16)°. In the crystal, mol-ecules are linked by N-H⋯S hydrogen-bond inter-actions, forming centrosymmetric dimers. Additionally, one weak intra-molecular N-H⋯N hydrogen-bond inter-action is observed. The crystal packing shows a herringbone arrangement viewed along the c axis.

Keywords: crystal structure.