{4-Amino-N'-[(2-oxidonaphthalen-1-yl)methyl-idene]benzohydrazidato}di-methyl-tin(IV)

Miao Cheng; Yuhong Zhao; Tiantian Dong; Jichun Cui

doi:10.1107/S1600536814014652

{4-Amino-N'-[(2-oxidonaphthalen-1-yl)methyl-idene]benzohydrazidato}di-methyl-tin(IV)

Acta Crystallogr Sect E Struct Rep Online. 2014 Jun 25;70(Pt 7):m283. doi: 10.1107/S1600536814014652. eCollection 2014 Jul 1.

Authors

Miao Cheng¹, Yuhong Zhao¹, Tiantian Dong¹, Jichun Cui¹

Affiliation

¹ College of Chemistry and Chemical Engineering, Liaocheng University, Shandong 252059, People's Republic of China.

Abstract

In the title compound, [Sn(CH3)2(C18H13N3O2)], the Sn(IV) ion is coordinated by one N and two O atoms from the tridentate 4-amino-N'-[(2-oxidonaphthalen-1-yl)methyl-idene]benzohydrazidate(2-) ligand and two C atoms from methyl ligands in a distorted trigonal-bipyramidal geometry. The dihedral angle between the naphthalene ring system and the benzene ring is 19.2 (2)°. In the crystal, weak N-H⋯O hydrogen bonds link the mol-ecules into zigzag chains along [010].

Keywords: crystal structure.