Sharp and fast: sensors and switches based on polymer brushes with adsorption-active minority chains

Phys Rev Lett. 2014 Aug 8;113(6):068303. doi: 10.1103/PhysRevLett.113.068303. Epub 2014 Aug 8.

Abstract

We propose a design for polymer-based sensors and switches with sharp switching transition and fast response time. The switching mechanism involves a radical change in the conformations of adsorption-active minority chains in a brush. Such transitions can be induced by a temperature change of only about ten degrees, and the characteristic time of the conformational change is less than a second. We present an analytical theory for these switches and support it by self-consistent field calculations and Brownian dynamics simulations.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Kinetics
  • Models, Chemical*
  • Molecular Conformation
  • Polymers / chemistry*
  • Thermodynamics

Substances

  • Polymers