Bronze, silver and gold: functionalized group 11 organotin sulfide clusters

Jens P Eussner; Stefanie Dehnen

doi:10.1039/c4cc05666c

Bronze, silver and gold: functionalized group 11 organotin sulfide clusters

Chem Commun (Camb). 2014 Oct 7;50(77):11385-8. doi: 10.1039/c4cc05666c.

Authors

Jens P Eussner¹, Stefanie Dehnen

Affiliation

¹ Philipps-Universität Marburg, Fachbereich Chemie and Wissenschaftliches Zentrum für Materialwissenschaften (WZMW), Hans-Meerwein-Straße, D-35043 Marburg, Germany. dehnen@chemie-uni-marburg.de.

PMID: 25123147
DOI: 10.1039/c4cc05666c

Abstract

The synthesis, properties and reactivity of group 11 organotin sulfide clusters [(R(1)Sn)4(SnCl)2(MPPh3)2S8] (M = Cu, Ag), [(R(3)Sn)10Ag10S20], and [(R(1,3)Sn)2(AuPPh3)2S4] with covalently bound, carbonyl or hydrazine-terminated ligands R(1) = CMe2CH2C(Me)O or R(3) = CMe2CH2C(Me)NNH2 are reported.