Reduction of CO2 to free CO by a Pd(I)-Pd(I) dimer

Chandra Mouli Palit; Daniel J Graham; Chun-Hsing Chen; Bruce M Foxman; Oleg V Ozerov

doi:10.1039/c4cc02438a

Reduction of CO2 to free CO by a Pd(I)-Pd(I) dimer

Chem Commun (Camb). 2014 Nov 4;50(85):12840-2. doi: 10.1039/c4cc02438a.

Authors

Chandra Mouli Palit¹, Daniel J Graham, Chun-Hsing Chen, Bruce M Foxman, Oleg V Ozerov

Affiliation

¹ Department of Chemistry, Texas A&M University, College Station, Texas 77843-3255, USA. ozerov@chem.tamu.edu.

PMID: 25068153
DOI: 10.1039/c4cc02438a

Abstract

Reaction of CO2 with a Pd(I)-Pd(I) dimer supported by amido/bis(phosphine) pincer PNP ligands produces free CO in the presence of Me3SiCl and Me3SiOTf.