Abstract
A palladium-catalyzed oxidative cross-coupling of vinyl boronic acids and cyclic α-diazocarbonyl compounds has been reported. The reaction constitutes an efficient method for the synthesis of 1,3-diene compounds bearing a ring structure. Mechanistically, the reaction involves migratory insertion of palladium carbene as the key step.
Publication types
-
Research Support, Non-U.S. Gov't
MeSH terms
-
Alkenes / chemical synthesis*
-
Alkenes / chemistry
-
Azo Compounds / chemistry*
-
Boronic Acids / chemistry*
-
Methane / analogs & derivatives*
-
Methane / chemistry
-
Molecular Structure
-
Oxidation-Reduction
-
Palladium / chemistry*
-
Vinyl Compounds / chemistry*
Substances
-
Alkenes
-
Azo Compounds
-
Boronic Acids
-
Vinyl Compounds
-
carbene
-
Palladium
-
Methane