Colloidal crystals in anisotropic matrices are extremely stable and versatile, but disassemble as soon as the anisotropy of the matrix disappears. We present an approach to first custom-assemble colloidal structures and subsequently stabilize them through photo-polymerisation of the liquid crystalline matrix. The resulting 2D colloidal assemblies are stable at high temperatures and can even be obtained as free-standing films without a decrease in the degree of organization. This approach could be used to stabilize and extract recently proposed soft-matter photonic microcircuits based on liquid crystal optical microresonators, microlasers and microfibers, and opens up routes towards real soft matter photonic devices that are stable over extended time and temperatures.