3-Iodo-1H-pyrazolo-[3,4-b]pyridine

Acta Crystallogr Sect E Struct Rep Online. 2014 May 10;70(Pt 6):o650. doi: 10.1107/S1600536814010009. eCollection 2014 Jun 1.

Abstract

The title compound, C6H4IN3, is essentially planar, with a dihedral angle of 0.82 (3)° between the planes of the pyridine and pyrazole rings. In the crystal, pairs of mol-ecules are connected into inversion dimers through N-H⋯N hydrogen bonds. C-I⋯N halogen bonds link the dimers into zigzag chains parallel to the b-axis direction. The packing also features π-π stacking inter-actions along (110) with inter-planar distances of 3.292 (1) and 3.343 (1) Å, and centroid-centroid distances of 3.308 (1) and 3.430 (1) Å.