Bis(cyclo-hexyl-ammonium) tetra-chlorido-diphenyl-stannate(IV)

Acta Crystallogr Sect E Struct Rep Online. 2014 May 17;70(Pt 6):m220-1. doi: 10.1107/S160053681401109X. eCollection 2014 Jun 1.

Abstract

The title compound, (C6H14N)2[Sn(C6H5)2Cl4], contains cyclo-hexyl-ammonium cations in general positions and a stannate(IV) anion that is located on a twofold rotation axis. The Sn(IV) atom in the complex anion is surrounded by four Cl(-) ligands and two trans-phenyl groups in a distorted octa-hedral configuration. The anions are connected with the cations through N-H⋯Cl hydrogen bonds. Every cation is involved in three N-H⋯Cl bonds to the chloride ligands of three different anions, and each chloride ligand is linked to two cations. This arrangement leads to a layered structure parallel to (010).