Platinum corroles

Chem Commun (Camb). 2014 Oct 4;50(76):11093-6. doi: 10.1039/c4cc02548b.

Abstract

Platinum has been inserted into corroles for the first time and three oxidized Pt(IV)(corrole˙(2-))ArAr' complexes have been structurally characterized. The Soret maxima of these complexes exhibit an unusually strong dependence on the meso-aryl substituents on the corrole, indicating aryl → corrole˙(2-) charge transfer character in these transitions.