A simple cubic structure with one atom in the unit cell found in compressed calcium is counterintuitive to the traditional view of a tendency towards densely packed structures with an increase in pressure. To understand this unusual transformation it is necessary to assume electron transfer from the outer core band to the valence band, and an increase of valence electron number for calcium from 2 to ∼ 3.5. This assumption is supported by the Fermi sphere-Brillouin zone interaction model that increases under compression. The recently found structure of Ca-VII with a tetragonal cell containing 32 atoms (tI32) is similar to that in the intermetallic compound In5Bi3 with 3.75 valence electrons per atom. Structural relations are analyzed in terms of electronic structure resemblance. Correlations of structure and physical properties of Ca are discussed.
Keywords: close-packed structures; compressed calcium; electronic structure.