Abstract
The ruthenium-catalyzed oxidative allylation of aromatic and α,β-unsaturated carboxamides with allylic carbonates is described. These transformations proceed readily with complete linear γ-selectivity of substituted allylic carbonates.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Allyl Compounds / chemical synthesis*
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Benzamides / chemical synthesis*
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Carbonates / chemical synthesis
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Catalysis
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Palladium / chemistry
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Pyrrolidines / chemical synthesis*
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Rhodium / chemistry
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Ruthenium / chemistry*
Substances
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Allyl Compounds
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Benzamides
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Carbonates
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Pyrrolidines
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Palladium
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Ruthenium
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Rhodium