Methyl 1-ethyl-3'-[hy-droxy(naphthalen-1-yl)meth-yl]-1'-methyl-2-oxo-spiro-[indo-line-3,2'-pyrrolidine]-3'-carboxyl-ate

Vinodhkumar Vijayakumar; Gunther H Peters; M Suresh; Raghunathan Raghavachary; G Jagadeesan

doi:10.1107/S1600536814007065

Methyl 1-ethyl-3'-[hy-droxy(naphthalen-1-yl)meth-yl]-1'-methyl-2-oxo-spiro-[indo-line-3,2'-pyrrolidine]-3'-carboxyl-ate

Acta Crystallogr Sect E Struct Rep Online. 2014 Apr 12;70(Pt 5):o540. doi: 10.1107/S1600536814007065. eCollection 2014 May 1.

Authors

Vinodhkumar Vijayakumar¹, Gunther H Peters², M Suresh³, Raghunathan Raghavachary³, G Jagadeesan⁴

Affiliations

¹ Department of Life Sciences and Chemistry, Roskilde University, DK-4000 Roskilde, Denmark.
² Department of Chemistry, Technical University of Denmark, 2800 Kgs. Lyngby, Denmark.
³ Department of Organic Chemistry, University of Madras, Guindy Campus, Chennai 600 025, India.
⁴ Department of Physics, Presidency College, Chennai 600 005, India.

Abstract

In the title compound, C27H28N2O4, the pyrrolidine ring adopts a twist conformation. The plane of the indole ring is almost perpendicular to that of the pyrrolidine ring, making a dihedral angle of 88.50 (6)°. The planes of the naphthyl ring system and the pyrrolidine ring are tilted by an angle of 55.86 (5)°. The mol-ecular conformation is stabilized by intra-molecular O-H⋯O and O-H⋯N hydrogen bonds.