2-(5-Chloro-2-oxoindolin-3-yl-idene)hydrazinecarbo-thio-amide

Acta Crystallogr Sect E Struct Rep Online. 2013 Dec 14;70(Pt 1):o64-5. doi: 10.1107/S1600536813033369. eCollection 2014 Jan 1.

Abstract

The title mol-ecule, C9H7ClN4OS, is almost planar, with an r.m.s. deviation of 0.034 (2) Å for the mean plane through all the non-H atoms. Intra-molecular N-H⋯O and N-H⋯N hydrogen bonds form S(6) and S(5) ring motifs, respectively. In the crystal, mol-ecules are assembled into inversion dimers through pairs of co-operative N-H⋯Cl inter-actions. These dimers are connected along the b axis by N-H⋯O and N-H⋯S hydrogen bonds, generating layers parallel to (103). The layers are further connected along the a axis into a three-dimensional network, through weak π-π stacking inter-actions [centroid-centroid distance = 3.849 (2) Å].