Di-chlorido-[N-(N,N-di-methyl-carbamimido-yl)-N',N',4-tri-methyl-benzohydrazonamide]-platinum(II) nitro-methane hemisolvate

Dmitrii S Bolotin; Nadezha A Bokach; Matti Haukka

doi:10.1107/S1600536814003894

Di-chlorido-[N-(N,N-di-methyl-carbamimido-yl)-N',N',4-tri-methyl-benzohydrazonamide]-platinum(II) nitro-methane hemisolvate

Acta Crystallogr Sect E Struct Rep Online. 2014 Mar 12;70(Pt 4):m131-2. doi: 10.1107/S1600536814003894. eCollection 2014 Apr 1.

Authors

Dmitrii S Bolotin¹, Nadezha A Bokach¹, Matti Haukka²

Affiliations

¹ Department of Chemistry, Saint Petersburg State University, Universitetsky Pr. 26, 198504 Stary Petergof, Russian Federation.
² Department of Chemistry, University of Jyväskylä, Finland, PO Box 35, FI-40014University of Jyväskylä, Finland.

Abstract

In the title compound, [PtCl2(C13H21N5)]·0.5CH3NO2, the Pt(II) atom is coordinated in a slightly distorted square-planar geometry by two Cl atoms and two N atoms of the bidentate ligand. The (1,3,5-tri-aza-penta-diene)Pt(II) metalla ring is slightly bent and does not conjugate with the aromatic ring. In the crystal, N-H⋯Cl hydrogen bonds link the complex mol-ecules, forming chains along [001]. The nitromethane solvent molecule shows half-occupancy and is disordered over two sets of sites about an inversion centre.