Efficient CO₂ capture by a task-specific porous organic polymer bifunctionalized with carbazole and triazine groups

Xiang Zhu; Shannon M Mahurin; Shu-Hao An; Chi-Linh Do-Thanh; Chengcheng Tian; Yankai Li; Lance W Gill; Edward W Hagaman; Zijun Bian; Jian-Hai Zhou; Jun Hu; Honglai Liu; Sheng Dai

doi:10.1039/c4cc01588f

Efficient CO₂ capture by a task-specific porous organic polymer bifunctionalized with carbazole and triazine groups

Chem Commun (Camb). 2014 Jul 28;50(59):7933-6. doi: 10.1039/c4cc01588f.

Authors

Xiang Zhu¹, Shannon M Mahurin, Shu-Hao An, Chi-Linh Do-Thanh, Chengcheng Tian, Yankai Li, Lance W Gill, Edward W Hagaman, Zijun Bian, Jian-Hai Zhou, Jun Hu, Honglai Liu, Sheng Dai

Affiliation

¹ State Key Laboratory of Chemical Engineering and Department of Chemistry, East China University of Science and Technology, Shanghai, 200237, China. hlliu@ecust.edu.cn.

PMID: 24825501
DOI: 10.1039/c4cc01588f

Abstract

A porous triazine and carbazole bifunctionalized task-specific polymer has been synthesized via a facile Friedel-Crafts reaction. The resultant porous framework exhibits excellent CO2 uptake (18.0 wt%, 273 K and 1 bar) and good adsorption selectivity for CO2 over N2.