Tunable antireflection from conformal Al-doped ZnO films on nanofaceted Si templates

Nanoscale Res Lett. 2014 Apr 26;9(1):192. doi: 10.1186/1556-276X-9-192. eCollection 2014.

Abstract

Photon harvesting by reducing reflection loss is the basis of photovoltaic devices. Here, we show the efficacy of Al-doped ZnO (AZO) overlayer on ion beam-synthesized nanofaceted silicon for suppressing reflection loss. In particular, we demonstrate thickness-dependent tunable antireflection (AR) from conformally grown AZO layer, showing a systematic shift in the reflection minima from ultraviolet to visible to near-infrared ranges with increasing thickness. Tunable AR property is understood in light of depth-dependent refractive index of nanofaceted silicon and AZO overlayer. This improved AR property significantly increases the fill factor of such textured heterostructures, which reaches its maximum for 60-nm AZO compared to the ones based on planar silicon. This thickness matches with the one that shows the maximum reduction in surface reflectance.

Pacs: 81.07.-b; 42.79.Wc; 81.16.Rf; 81.15.Cd.

Keywords: Aluminum-doped zinc oxide; Antireflection property; Ion beam-induced nanopatterning; Silicon; Sputter deposition.