Degradation of methylparaben in water by corona plasma coupled with ozonation

Environ Sci Pollut Res Int. 2014 Nov;21(21):12190-7. doi: 10.1007/s11356-014-2964-y. Epub 2014 May 8.

Abstract

The degradation of methylparaben (MeP) in water was investigated using a pulsed corona discharge generated in oxygen, above the liquid. A comparison was made between results obtained in semi-batch corona (SBC) configuration (stationary solution, continuous gas flow) and results obtained in a semi-batch corona with recirculation combined with ozonation (SBCR + O3), where the liquid is continuously circulated between a solution reservoir and the plasma reactor and the effluent gas containing ozone is bubbled through the solution in the reservoir. It was found that MeP was completely degraded after 10-15 min of treatment in both configurations. Oxidation by ozone alone, in the absence of plasma, was a slower process. The energy efficiency for MeP removal (Y MeP) and for mineralization (Y TOC) was significantly higher in the SBCR + O3 configuration (Y MeP = 7.1 g/kWh at 90 % MeP removal and Y TOC = 0.41 g/kWh at 50 % total organic carbon (TOC) removal) than in the SBC configuration (Y MeP = 0.6 g/kWh at 90 % MeP removal and Y TOC = 0.11 g/kWh at 50 % TOC removal).

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Electrochemical Techniques
  • Kinetics
  • Oxidation-Reduction
  • Oxygen / chemistry
  • Ozone / chemistry*
  • Parabens / chemistry*
  • Water Pollutants, Chemical / chemistry*
  • Water Purification / instrumentation
  • Water Purification / methods*

Substances

  • Parabens
  • Water Pollutants, Chemical
  • Ozone
  • methylparaben
  • Oxygen