catena-Poly[[bis-(ethanol-κO)mangan-ese(II)]-μ-2,5-di-chloro-3,6-di-oxo-cyclo-hexa-1,4-diene-1,4-bis-(olato)-κ(4) O (1),O (6):O (3),O (4)]

Seiya Tanaka; Akiko Himegi; Tomomi Ohishi; Akira Fuyuhiro; Satoshi Kawata

doi:10.1107/S1600536814002396

catena-Poly[[bis-(ethanol-κO)mangan-ese(II)]-μ-2,5-di-chloro-3,6-di-oxo-cyclo-hexa-1,4-diene-1,4-bis-(olato)-κ(4) O (1),O (6):O (3),O (4)]

Acta Crystallogr Sect E Struct Rep Online. 2014 Feb 8;70(Pt 3):m90-1. doi: 10.1107/S1600536814002396. eCollection 2014 Mar 1.

Authors

Seiya Tanaka¹, Akiko Himegi¹, Tomomi Ohishi¹, Akira Fuyuhiro², Satoshi Kawata¹

Affiliations

¹ Department of Chemistry, Faculty of Science, Fukuoka University, Nanakuma, Jonan-ku, Fukuoka 814-0180, Japan.
² Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan.

Abstract

In the title coordination polymer, [Mn(C6Cl2O4)(C2H5OH)2] n , the Mn(II) atom and the chloranilate [systematic name: 2,5-di-chloro-3,6-dioxo-cyclo-hexa-1,4-diene-1,4-bis-(olate)] ion lie on crystallographic inversion centers. The geometry around the Mn(II) atom is a distorted octa-hedron involving four O atoms of two chloranilate ions and two O atoms from two ethanol mol-ecules. The chloranilate ion serves as a bridging ligand between the Mn(II) ions, leading to an infinite linear chain along the b-axis direction. The chains are linked by O-H⋯O hydrogen bonds between the apically coordinating ethanol mol-ecule and the chloranilate ion, affording a two-dimensional layer expanding parallel to the ab plane.