Di-chlorido-dimethyl-bis-(thio-urea-κS)tin(IV)

Acta Crystallogr Sect E Struct Rep Online. 2014 Feb 8;70(Pt 3):m83. doi: 10.1107/S1600536814002025. eCollection 2014 Mar 1.

Abstract

The title compound, [Sn(CH3)2Cl2(CH4N2S)2], crystallizes with two half-mol-ecules in the asymmetric unit. Both mol-ecules are completed by inversion symmetry with the two Sn(IV) atoms located on inversion centers. The metal atoms have distorted octa-hedral coordination environments defined by two Cl atoms, two C atoms of methyl groups and two thio-urea S atoms. In the crystal, mol-ecules are linked via N-H⋯Cl and N-H⋯S hydrogen bonds, forming a three-dimensional structure.