Tetra-chloridodi-μ3-oxido-tetra-kis-(μ2-propan-2-olato-κ(2) O:O)ditin(II)ditin(IV)

Oleg Yarushnikov; Dina Naumova; Nikolai Klishin; Eduard Rusanov; Oleksii Brusylovets

doi:10.1107/S1600536814000816

Tetra-chloridodi-μ3-oxido-tetra-kis-(μ2-propan-2-olato-κ(2) O:O)ditin(II)ditin(IV)

Acta Crystallogr Sect E Struct Rep Online. 2014 Jan 18;70(Pt 2):m45-6. doi: 10.1107/S1600536814000816. eCollection 2014 Feb 1.

Authors

Oleg Yarushnikov¹, Dina Naumova¹, Nikolai Klishin¹, Eduard Rusanov², Oleksii Brusylovets¹

Affiliations

¹ Department of Chemistry, Kiev National Taras Shevchenko University, Volodymyrska Street 64, 01601 Kiev, Ukraine.
² Institute of Organic Chemistry, Murmanskaya Street 4, 253660, Ukraine.

Abstract

The centrosymmetric tetranuclear title molecule, [Sn4(C3H7O)4Cl4O2], contains two types of Sn atoms, Sn(II) and Sn(IV). The Sn(II) atom has a trigonal-pyramidal coordination environment and is bonded to two O atoms from two iso-propano-late groups and one μ3-oxide atom. The Sn(IV) atom has an octa-hedral coordination environment, formed by two chloride atoms, two μ3-oxide atoms and two O atoms from iso-propano-late groups.