Abstract
Azide-tagged Cu(I)-NHC reacts in an 'auto-click' process to furnish complexes functionalized by 1,2,3-triazoles bearing diverse substituents. The resulting Cu(I) complexes are amenable to further transmetallation to Au(I). The whole strategy proceeds with mild conditions and constitutes an efficient entry to functionalised metal-NHCs with biorelevant moieties.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Cell Line, Tumor
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Click Chemistry
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Coordination Complexes / chemical synthesis
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Coordination Complexes / chemistry
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Coordination Complexes / metabolism
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Copper / chemistry*
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Crystallography, X-Ray
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Gold / chemistry*
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Heterocyclic Compounds / chemistry*
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Humans
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Microscopy, Confocal
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Molecular Conformation
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Triazoles / chemistry
Substances
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Coordination Complexes
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Heterocyclic Compounds
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Triazoles
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Gold
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Copper