Potassium phthalimide, with weak basicity, is an excellent absorbent for rapid carbon dioxide capture with almost equimolar absorption. This process is assumed to proceed through the potassium carbamate formation pathway, as supported by NMR spectroscopy, an in situ FTIR study, and computational calculations. Both the basicity and nucleophilicity of phthalimide salts have a crucial effect on the capture process. Furthermore, the captured carbon dioxide could more easily be converted in situ into value-added chemicals and fuel-related products through carbon capture and utilization, rather than going through a desorption process.
Keywords: absorption; carbon dioxide fixation; green chemistry; homogeneous catalysis; phthalimides; potassium.
© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.