Cosmetic wastewater treatment by coagulation and advanced oxidation processes

Environ Technol. 2014 Mar-Apr;35(5-8):541-8. doi: 10.1080/09593330.2013.808245.

Abstract

In this study, the treatment process of three cosmetic wastewater types has been investigated. Coagulation allowed to achieve chemical oxygen demand (COD) removal of 74.6%, 37.7% and 74.0% for samples A (Al2(SO4)3), B (Brentafloc F3) and C (PAX 16), respectively. The Fenton process proved to be effective as well - COD removal was equal to 75.1%, 44.7% and 68.1%, respectively. Coagulation with FeCl3 and the subsequent photo-Fenton process resulted in the best values of final COD removal equal to 92.4%, 62.8% and 90.2%. In case of the Fenton process, after coagulation these values were equal to 74.9%, 50.1% and 84.8%, while in case of the H2O2/UV process, the obtained COD removal was 83.8%, 36.2% and 80.9%. High value of COD removal in the Fenton process carried out for A and C wastewater samples was caused by a significant contribution of the final neutralization/coagulation. Very small effect of the oxidation reaction in the Fenton process in case of sample A resulting from the presence of antioxidants, 'OH radical scavengers' in the wastewater.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Alum Compounds / chemistry
  • Antioxidants / chemistry
  • Biological Oxygen Demand Analysis
  • Chlorides / chemistry
  • Cosmetics / analysis*
  • Ferric Compounds / chemistry
  • Free Radical Scavengers / chemistry
  • Hydrogen Peroxide / chemistry
  • Hydrogen-Ion Concentration
  • Hydroxyl Radical / chemistry
  • Industrial Waste
  • Iron / chemistry
  • Nephelometry and Turbidimetry
  • Oxygen / chemistry*
  • Waste Disposal, Fluid / methods
  • Wastewater
  • Water Pollutants
  • Water Pollutants, Chemical / analysis*
  • Water Pollutants, Chemical / chemistry
  • Water Purification / methods*

Substances

  • Alum Compounds
  • Antioxidants
  • Chlorides
  • Cosmetics
  • Fenton's reagent
  • Ferric Compounds
  • Free Radical Scavengers
  • Industrial Waste
  • Waste Water
  • Water Pollutants
  • Water Pollutants, Chemical
  • Hydroxyl Radical
  • aluminum sulfate
  • Hydrogen Peroxide
  • Iron
  • Oxygen
  • ferric chloride