Visible-light photochemical activity of nanoporous carbons under monochromatic light

Angew Chem Int Ed Engl. 2014 Apr 14;53(16):4146-8. doi: 10.1002/anie.201400887. Epub 2014 Mar 12.

Abstract

By using monochromatic light the ability of semiconductor-free nanoporous carbons to convert the low-energy photons from the visible spectrum into chemical reactions (i.e. phenol photooxidation) is demonstrated. Data shows that the onset wavelength of the photochemical activity can be tuned by surface functionalization, with enhanced visible-light conversion upon introducing N-containing groups.

Keywords: nanoporous carbon; photochemistry; surface functionalization; visible light.