Magnetic ordering in TmGa

J Phys Condens Matter. 2014 Mar 19;26(11):116002. doi: 10.1088/0953-8984/26/11/116002. Epub 2014 Mar 3.

Abstract

We have determined the magnetic structure of the intermetallic compound TmGa by high-resolution neutron powder diffraction and (169)Tm Mössbauer spectroscopy. This compound crystallizes in the orthorhombic (Cmcm) CrB-type structure and its magnetic structure is characterized by magnetic order of the Tm sublattice along the a-axis. The initial magnetic ordering occurs at 15(1) K and yields an incommensurate antiferromagnetic structure described by the propagation vector k1 = [0 0.275(2) 0]. At 12 K the dominant ferromagnetic ordering of the Tm sublattice along the a-axis develops in what appears to be a first-order transition. At 3 K the magnetic structure of TmGa is predominantly ferromagnetic but a weakened incommensurate component remains. The ferromagnetic Tm moment reaches 6.7(2) μB at 3 K and the amplitude of the remaining incommensurate component is 2.7(4) μB. The (169)Tm hyperfine magnetic field at 5 K is 631(1) T.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Crystallization
  • Crystallography, X-Ray
  • Gallium / chemistry*
  • Magnetic Phenomena*
  • Magnets / chemistry*
  • Models, Molecular
  • Neutron Diffraction
  • Powder Diffraction
  • Spectroscopy, Mossbauer
  • Temperature
  • Thulium / chemistry*

Substances

  • Thulium
  • Gallium