Magnetic mesoporous Fe/carbon aerogel structures with enhanced arsenic removal efficiency

J Colloid Interface Sci. 2014 Apr 15:420:74-9. doi: 10.1016/j.jcis.2014.01.008. Epub 2014 Jan 15.

Abstract

Wastewater treatment has drawn significant research attention due to its associated environmental issues. Adsorption is a promising method for treating wastewater. The development of an adsorbent with a high surface area is important. Therefore, we successfully developed mesoporous Fe/carbon aerogel (CA) structures with high specific surface areas of 48 7m(2)/g via the carbonization of composite Fe3O4/phenol-formaldehyde resin structures, which were prepared using a hydrothermal process with the addition of phenol. The mesoporous Fe/CA structures were further used for the adsorption of arsenic ions with a maximum arsenic-ion uptake of calculated 216.9 mg/g, which is higher than that observed for other arsenic adsorbents. Ferromagnetic behavior was observed for the as-prepared mesoporous Fe/CA structures with an excellent response to applied external magnetic fields. As a result, the adsorbent Fe/CA structures can be easily separated from the solution using an external magnetic field. This study develops the mesoporous Fe/CA structures with high specific surface areas and an excellent response to an applied external magnetic field to provide a feasible approach for wastewater treatment including the removal of arsenic ions.

Keywords: Adsorption; Arsenic ions; Fe/carbon aerogels; Mesoporous; Surface area.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Arsenic / chemistry*
  • Carbon / chemistry*
  • Ferric Compounds / chemistry*
  • Formaldehyde / chemistry*
  • Gels / chemistry
  • Phenols / chemistry*
  • Polymers / chemistry*
  • Porosity
  • Wastewater / chemistry*
  • Water Pollutants, Chemical / chemistry*
  • Water Purification / methods*

Substances

  • Ferric Compounds
  • Gels
  • Phenols
  • Polymers
  • Waste Water
  • Water Pollutants, Chemical
  • Formaldehyde
  • ferric oxide
  • Carbon
  • phenol-formaldehyde resin
  • Arsenic