Poly[(μ6-benzene-1,3,5-tri-carboxyl-ato-κ(6) O (1):O (1'):O (3):O (3'):O (5):O (5'))tris-(N,N-di-methyl-formamide-κO)tris-(μ3-formato-κ(3) O:O:O')trizinc(II)]

Jaeung Sim; Taemin Kim; Jin Kuk Yang

doi:10.1107/S1600536813028687

Poly[(μ6-benzene-1,3,5-tri-carboxyl-ato-κ(6) O (1):O (1'):O (3):O (3'):O (5):O (5'))tris-(N,N-di-methyl-formamide-κO)tris-(μ3-formato-κ(3) O:O:O')trizinc(II)]

Acta Crystallogr Sect E Struct Rep Online. 2013 Oct 26;69(Pt 11):m619. doi: 10.1107/S1600536813028687. eCollection 2013 Nov 1.

Authors

Jaeung Sim¹, Taemin Kim¹, Jin Kuk Yang¹

Affiliation

¹ Department of Chemistry, Soongsil University, 369 Sangdo-Ro, Dongjak-Gu, Seoul 156-743, Republic of Korea.

Abstract

The asymmetric unit of the title compound, [Zn3(HCO2)3(C9H3O6)(C3H7NO)3] n , contains one Zn ion, one formate ligand, one N,N-di-methyl-formamide (DMF) ligand and one-third of a benzene-1,3,5-tri-carboxyl-ate (btc) ligand situated on a crystallographic 3 axis. Each Zn(II) atom is coordinated by one O atom from a DMF ligand, two O atoms from two btc ligands and three O atoms from three formate ligands in a distorted octa-hedral geometry. The Zn(II) atoms are connected by the formate and btc ligands, forming hexanuclear cores, which are linked by btc ligands, constructing a two-dimensional layered network along the ab plane.